Please note that UPSpace will be unavailable from Friday, 2 May at 18:00 (South African Time) until Sunday, 4 May at 20:00 due to scheduled system upgrades. We apologise for any inconvenience this may cause and appreciate your understanding.
dc.contributor.upauthor | Boeyens, Jan Christoffel Antonie | |
dc.date.accessioned | 2014-06-04T10:26:46Z | |
dc.date.available | 2014-06-04T10:26:46Z | |
dc.date.issued | 2013 | |
dc.description.abstract | Some chemical phenomena, awkward to rationalize, are argued to originate in the four-dimensional nature of matter in curved space-time. The problem is traced back to the separation of space and time variables in the analysis of fourdimensional events. Althoughmathematically sound, this operation is not physically valid. It destroys the essential non-classical entanglement of space and time, which is recognized in relativistic theory, but not in quantum mechanics. We show that without this approximation the state functions of quantum theory have the same quaternion structure that describes Lorentz transformation and spin. Hypercomplex formulation of four-dimensional motion eliminates several bothersome concepts, such as wave-particle duality and probability density, by providing the logical basis for non-zero commutators in non-classical systems. It shows why chiral states are undefined in quantum theory and why many solid-state transitions appear to be sterically forbidden. A brief introduction to hypercomplex algebra is given as an Appendix. | en_US |
dc.description.librarian | hj2014 | en_US |
dc.description.uri | http://www.springer.com/series/430 | en_US |
dc.identifier.citation | Boeyens, JCA 2013, 'Chemistry in four dimensions', Structure and Bonding, vol. 148, pp. 25-47. | en_US |
dc.identifier.issn | 0081-5993 | |
dc.identifier.uri | http://hdl.handle.net/2263/39989 | |
dc.language.iso | en | en_US |
dc.publisher | Springer | en_US |
dc.rights | © Springer-Verlag Berlin Heidelberg 2013. The original publication is available at : http://www.springer.com/series/430 | en_US |
dc.subject | d’Alembertian | en_US |
dc.subject | Dirac’s equation | en_US |
dc.subject | Harmonic function | en_US |
dc.subject | Spin function | en_US |
dc.subject | Quaternion | en_US |
dc.title | Chemistry in four dimensions | en_US |
dc.type | Postprint Article | en_US |