1,3-Bis(2,4,6-trimethylphenyl)-3H imidazol-1-ium tetraoxidorhenate(VII)

Landman, Marile; Van der Westhuizen, Belinda; Bezuidenhout, Daniela Ina; Liles, David C.

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1,3-Bis(2,4,6-trimethylphenyl)-3H imidazol-1-ium tetraoxidorhenate(VII)

Landman, Marile; Van der Westhuizen, Belinda; Bezuidenhout, Daniela Ina; Liles, David C.

URI: http://hdl.handle.net/2263/19238

Date: 2011

Abstract:

The title compound, (C21H25N2)[ReO4], was formed as the unexpected product in an attempted synthesis of a rhenium(I)–N-heterocyclic carbene (NHC) complex. The compound has crystallographic mirror symmetry with both the cation and the tetrahedral anion located across a mirror plane. The cation and anion are linked by a C—H O hydrogen bond.

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